The score says how it ended. xG says how it should have ended: it is the sum of the chances each shot was worth, not an opinion about the game.
The score matched the game: AC Milan was the better side by chances too.
AC Milan: +2.1 for the season (5 in the table). Venezia: −5.5 (20). The gap between points and xPTS is built from matches like this one.